Outputs (36)

Structural markers of the Frenkel line in the proximity of Widom lines (2021)
Journal Article
Pruteanu, C., Proctor, J., Alderman, O., & Loveday, J. (2021). Structural markers of the Frenkel line in the proximity of Widom lines. Journal of Physical Chemistry B, 125(31), 8902-8906. https://doi.org/10.1021/acs.jpcb.1c04690

We have performed a neutron scattering experiment on supercritical
uid nitrogen
at 160 K (1.27 TC) over a wide pressure range (7.8 MPa / 0.260 g/ml to 125 MPa /
0.805 g/ml). This has enabled us to study the process by which nitrogen changes from... Read More about Structural markers of the Frenkel line in the proximity of Widom lines.

Mechanical properties of graphene (2021)
Journal Article

This paper reviews the mechanical properties of graphene with particular attention to what is established and what is still uncertain. It clarifies the thickness and the elastic constants, and by also considering also phonon frequencies, it argues th... Read More about Mechanical properties of graphene.

Modeling of liquid internal energy and heat capacity over a wide pressure–temperature range from first principles (2020)
Journal Article
Proctor, J. (2020). Modeling of liquid internal energy and heat capacity over a wide pressure–temperature range from first principles. Physics of Fluids, 32, 107105. https://doi.org/10.1063/5.0025871

Recently, there have been significant theoretical advances in our understanding of liquids and dense supercritical fluids based on their ability to support high frequency transverse (shear) waves. Here, we have constructed a new computer model using... Read More about Modeling of liquid internal energy and heat capacity over a wide pressure–temperature range from first principles.

The liquid and supercritical fluid states of matter (2020)
Book
Proctor, J. (2020). The liquid and supercritical fluid states of matter. CRC Press (Taylor and Francis). https://doi.org/10.1201/9780429491443

This book addresses graduate students and researchers wishing to better understand the liquid and supercritical fluid states of matter, presenting a single cohesive treatment of the liquid and supercritical fluid states using the gas-like and solid-l... Read More about The liquid and supercritical fluid states of matter.

Raman spectroscopy of ethane (C 2 H 6 ) to 120 GPa at 300 K (2020)
Journal Article
Read, L., Spender, J., & Proctor, J. (2020). Raman spectroscopy of ethane (C 2 H 6 ) to 120 GPa at 300 K. Journal of Raman Spectroscopy, 51(11), 2311-2317. https://doi.org/10.1002/jrs.5971

We have conducted a Raman study of solid ethane (C2H6) at pressures up to 120 GPa at 300 K. We observe changes within the ν3 and ν11 Raman‐active vibrational modes providing evidence for several previously unobserved phase transitions at room tempera... Read More about Raman spectroscopy of ethane (C 2 H 6 ) to 120 GPa at 300 K.

Experimental and theoretical confirmation of an orthorhombic phase transition in niobium at high pressure and temperature (2020)
Journal Article

Compared to other body-centered cubic (bcc) transition metals, Nb has been the subject of fewer compression studies and there are still aspects of its phase diagram which are unclear. Here, we report a combined theoretical and experimental study of N... Read More about Experimental and theoretical confirmation of an orthorhombic phase transition in niobium at high pressure and temperature.

Influence of synthesis conditions on the structure of nickel nanoparticles and their reactivity in selective asymmetric hydrogenation (2019)
Journal Article

Unsupported and SiO2-supported Ni nanoparticles (NPs), were synthesised via hot-injection colloidal route using oleylamine (OAm) and trioctylphosphine (TOP) as reducing and protective agents, respectively. By adopting a multi-length scale structural... Read More about Influence of synthesis conditions on the structure of nickel nanoparticles and their reactivity in selective asymmetric hydrogenation.

Transition from gas-like to liquid-like behavior in supercritical N2 (2019)
Journal Article
Proctor, J., Pruteanu, C., Morrison, I., Crowe, I., & Loveday, J. (2019). Transition from gas-like to liquid-like behavior in supercritical N2. Journal of Physical Chemistry Letters, 10(21), 6584-6589. https://doi.org/10.1021/acs.jpclett.9b02358

We have studied in detail the transition from gas-like to rigid liquidlike behavior in supercritical N2 at 300 K (2.4 TC). Our study combines neutron diffraction and Raman spectroscopy with ab initio molecular dynamics simulations. We observe a narr... Read More about Transition from gas-like to liquid-like behavior in supercritical N2.

Melting curve and phase diagram of vanadium under high-pressure and high-temperature conditions (2019)
Journal Article
Errandonea, D., Macleod, S., Burakovsky, L., Santamaria-Perez, D., Proctor, J., Cynn, H., & Mezouar, M. (2019). Melting curve and phase diagram of vanadium under high-pressure and high-temperature conditions. Physical Review B, 100(9), https://doi.org/10.1103/PhysRevB.100.094111

We report a combined experimental and theoretical study of the melting curve
and the structural behavior of vanadium under extreme pressure and temperature. We
performed powder x-ray diffraction experiments up to 120 GPa and 4000 K, determining
th... Read More about Melting curve and phase diagram of vanadium under high-pressure and high-temperature conditions.

Viewpoint : graphene is thin, but not infinitely so (2019)
Journal Article
Proctor, J. (2019). Viewpoint : graphene is thin, but not infinitely so. Physics - Spotlighting Exceptional Research, 12, 104-104. https://doi.org/10.1103/Physics.12.104

Atomically thin graphene is considered a prototypical 2D material, but high-pressure experiments now reveal the 3D nature of its mechanical properties.