The rise of electrochemical NAPXPS operated in the soft X-ray regime exemplified by the oxygen evolution reaction on IrO

Velasco Vélez, Juan Jesús; Bernsmeier, Denis; Jones, Travis E.; Zeller, Patrick; Carbonio, Emilia; Chuang, Cheng-Hao; Falling, Lorenz J.; Streibel, Verena; Mom, Rik V.; Hammud, Adnan; Hävecker, Michael; Arrigo, Rosa; Stotz, Eugen; Lunkenbein, Thomas; Knop-Gericke, Axel; Krähnert, Ralph; Schlögl, Robert

Abstract

Different operando approaches based in PES were used and compared under OER conditions on IrOx. ResPES indicates that single coordinated oxygen atoms (μ1-O) are the active species yielding the formation of peroxo (μ1-OO) and finally O2 as product.

Citation

Velasco Vélez, J. J., Bernsmeier, D., Jones, T. E., Zeller, P., Carbonio, E., Chuang, C., …Schlögl, R. (2022). The rise of electrochemical NAPXPS operated in the soft X-ray regime exemplified by the oxygen evolution reaction on IrO. Faraday Discussions, 236, 103-125. https://doi.org/10.1039/d1fd00114k

• Journal Article Type: Article
• Acceptance Date: Feb 8, 2022
• Online Publication Date: May 3, 2024
• Publication Date: Apr 29, 2022
• Deposit Date: Jul 26, 2022
• Publicly Available Date: Jul 26, 2022
• Journal: Faraday Discussions
• Print ISSN: 1359-6640
• Publisher: Royal Society of Chemistry
• Volume: 236
• Pages: 103-125
• DOI: https://doi.org/10.1039/d1fd00114k
• Publisher URL: https://doi.org/10.1039/D1FD00114K