NM Boag
Trans-Bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionato-kappa O-2,O ')bis(4-methyl-1,2,3-selenadiazole-kappa N-3)copper(II)
Boag, NM; Jackson, AD; Lickiss, PD; Pilkington, RD; Redhouse, AD
Authors
AD Jackson
PD Lickiss
RD Pilkington
AD Redhouse
Abstract
In the title compound, [Cu(C5HF6O2)(2)(C3H4N2Se)(2)], the Cu-II atom (site symmetry (1) over bar) is coordinated by two O,O'-bidentate 1,1,1,5,5,5-hexafluoro-2,4-pentanedione (hp) ligands and two 4-methyl-1,2,3-selenadiazole molecules, resulting in a slightly distorted trans-CuN2O4 octahedral geometry in which the cis angles deviate by less than 3 degrees from 90 degrees. The selenadiazole plane is canted at 73.13 (17)degrees to the square plane defined by the pentanedionate O atoms. The F atoms of one of the hp ligands are disordered over two sets of sites in a 0.66 (3):0.34 (3) ratio. There are no significant intermolecular interactions in the crystal.
Citation
Boag, N., Jackson, A., Lickiss, P., Pilkington, R., & Redhouse, A. (2010). Trans-Bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionato-kappa O-2,O ')bis(4-methyl-1,2,3-selenadiazole-kappa N-3)copper(II). Acta Crystallographica Section E: Crystallographic Communications, 66(2), M241. https://doi.org/10.1107/S1600536810001297
Journal Article Type | Article |
---|---|
Acceptance Date | Jan 11, 2010 |
Publication Date | Feb 1, 2010 |
Deposit Date | Jul 14, 2015 |
Publicly Available Date | Apr 5, 2016 |
Journal | Acta Crystallographica Section E : Structure Reports Online |
Electronic ISSN | 2056-9890 |
Publisher | International Union of Crystallography |
Peer Reviewed | Peer Reviewed |
Volume | 66 |
Issue | 2 |
Pages | M241 |
DOI | https://doi.org/10.1107/S1600536810001297 |
Publisher URL | http://dx.doi.org/10.1107/S1600536810001297 |
Related Public URLs | http://journals.iucr.org/e/ |
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