A Al-Otaify
Size dependence of ultrafast charge dynamics in monodisperse Au nanoparticles supported on TiO2 colloidal spheres
Al-Otaify, A; Leontiadou, M; dos Reis, FVE; Damato, TC; Camargo, PHC; Binks, DJ
Authors
Dr Marina Leontiadou M.Leontiadou@salford.ac.uk
Associate Professor/Reader
FVE dos Reis
TC Damato
PHC Camargo
DJ Binks
Abstract
Sub-nanosecond charge dynamics in monodisperse Au nanoparticles (NPs) supported on TiO2 colloidal spheres are studied as a function of NP diameter using ultrafast transient absorption spectroscopy. The decay of the transmittance changes observed in the region of the plasmon resonance of the Au NPs following photoexcitation of the TiO2 spheres are well-described by a bi-exponential function consisting of a fast component of 2 ps duration associated with electron–phonon scattering, followed by a slow and relatively weak component associated with phonon–phonon scattering. The decay constant characterising the latter component was found to be dependent on the size of the Au NPs, rising from 49 ± 3 to 128 ± 6 ps as the diameter of the Au NPs increased from 12.2 ± 2.2 nm to 24.5 ± 2.8 nm, respectively.
Citation
Al-Otaify, A., Leontiadou, M., dos Reis, F., Damato, T., Camargo, P., & Binks, D. (2014). Size dependence of ultrafast charge dynamics in monodisperse Au nanoparticles supported on TiO2 colloidal spheres. Physical Chemistry Chemical Physics, 16, 14189-14194. https://doi.org/10.1039/c4cp01475h
Journal Article Type | Article |
---|---|
Acceptance Date | Jun 2, 2014 |
Online Publication Date | Jun 2, 2014 |
Publication Date | Jun 2, 2014 |
Deposit Date | Apr 2, 2019 |
Journal | Physical Chemistry Chemical Physics |
Print ISSN | 1463-9076 |
Electronic ISSN | 1463-9084 |
Publisher | Royal Society of Chemistry |
Volume | 16 |
Pages | 14189-14194 |
DOI | https://doi.org/10.1039/c4cp01475h |
Publisher URL | https://doi.org/10.1039/c4cp01475h |
Related Public URLs | https://pubs.rsc.org/en/journals/journalissues/cp#!recentarticles&adv |
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