Effects of softwood biochar on the status of nitrogen species and elements of potential toxicity in soils

Heaney, N; Mamman, M; Tahir, H; Al-Gharib, A; Lin, C

Abstract

The effects of softwood-derived biochar materials on the chemical behaviour of environmental contaminants in
soils were examined in two microcosm scenarios. Addition of the biochar materials into an alkaline sandy soil
significantly reduced NH3 volatilization and made it available for conversion into NO3- via nitrification. This
process could be enhanced by an increased application rate of biochar produced at a higher pyrolysis temperature.
Under the alkaline conditions encountered in the experiment, the biochar surfaces tended to be negatively
charged which disfavours the adsorption of NO3-. Therefore, in a fully open system, the addition of
biochar materials was likely to contribute to nitrate leaching from the fertilized alkaline sandy soil. The effects of
the biochar materials on the immobilization of Fe2+ generated via anaerobic iron reduction in the inundated
contaminated soil were not observed, except for the treatment with a higher dose of biochar material produced
under pyrolysis temperature at 700°C after the 240th h of incubation. Arsenic showed similar behaviour to Fe.
Zn tended to have a higher affinity to the biochar, as compared to Mn. Immobilization of Pb occurred regardless
of whether or not the biochar is present.

Citation

Heaney, N., Mamman, M., Tahir, H., Al-Gharib, A., & Lin, C. (2018). Effects of softwood biochar on the status of nitrogen species and elements of potential toxicity in soils. Ecotoxicology and Environmental Safety, 166, 383-389. https://doi.org/10.1016/j.ecoenv.2018.09.112

• Journal Article Type: Article
• Acceptance Date: Sep 25, 2018
• Online Publication Date: Oct 1, 2018
• Publication Date: Oct 1, 2018
• Deposit Date: Oct 11, 2018
• Publicly Available Date: Oct 1, 2019
• Journal: Ecotoxicology and Environmental Safety
• Print ISSN: 0147-6513
• Publisher: Elsevier
• Volume: 166
• Pages: 383-389
• DOI: https://doi.org/10.1016/j.ecoenv.2018.09.112
• Publisher URL: https://doi.org/10.1016/j.ecoenv.2018.09.112
• Related Public URLs: https://www.journals.elsevier.com/ecotoxicology-and-environmental-safety